Efficient removal of oil pollutant via simultaneous adsorption and photocatalysis using La–N–TiO2–cellulose/SiO2 difunctional aerogel composite

Research on Chemical Intermediates - Nano-TiO2 photocatalysts doped with La–N(La–N–TiO2) were prepared by solgel method. The La–N–TiO2 was loaded on the cellulose/SiO2...     

传输线方程的高精度龙格−库塔数值求解方法

提出了一种求解传输线方程的高精度龙格-库塔(RK)方法。此方法在空间上采取高阶泰勒展开,提高了对空间微分的近似精度,减少了数值色散所带来的误差。与传统的时域有限差分法(FDTD)方法相比,在每波长采样数相同时,RK方法的计算精度更高。同时,根据Taylor模型,对外界平面波激励源进行离散,成功利用RK方法对外部场激励传输线进行求解,扩大了龙格-库塔方法在求解传输线方程时的应用范围。通过编程对平面波辐照下无限大地平面上的单导体与双导体的算例分别应用FDTD方法与RK方法进行了计算,验证了RK方法的正确性。结果表明同等计算条件下RK方法的计算精度更高。     

Time-dependent Ginzburg–Landau equations for multi-gap superconductors

We numerically solve the time-dependent Ginzburg–Landau equations for two-gap superconductors using the finite-element technique. The real-time simulation shows that at low magnetic field, the vortices in small-size samples tend to form clusters or other disorder structures. When the sample size is large, stripes appear in the pattern. These results are in good agreement with the previous experimental observations of the intriguing anomalous vortex pattern, providing a reliable theoretical basis for the future applications of multi-gap superconductors.     

Iron porphyrin catalysed light driven C–H bond amination and alkene aziridination with organic azides

Visible light driven nitrene transfer and insertion reactions of organic azides are an attractive strategy for the design of C–N bond formation reactions under mild reaction conditions, the challenge being lack of selectivity as a free nitrene reactive intermediate is usually involved. Herein is described an iron(iii) porphyrin catalysed sp³ C–H amination and alkene aziridination with selectivity by using organic azides as the nitrogen source under blue LED light (469 nm) irradiation. The photochemical reactions display chemo- and regio-selectivity and are effective for the late-stage functionalization of natural and bioactive compounds with complexity. Mechanistic studies revealed that iron porphyrin plays a dual role as a photosensitizer and as a catalyst giving rise to a reactive iron–nitrene intermediate for subsequent C–N bond formation.

An iron(iii) porphyrin catalysed sp³ C–H amination and alkene aziridination with broad substrate scope under mild conditions is conducted, with selectivity through the use of organic azides as the nitrogen source under blue LED light irradiation.     

Multi-reference lens-less Fourier-transform holography with a Greek-ladder sieve array

Lens-less Fourier-transform holography has been actively studied because of its simple optical structure and its single-shot recording.However,a low-contrast interferogram between the reference and object waves limits its signal to noise ratio.Here,multi-reference lens-less Fourier-transform holography with a Greek-ladder sieve array is proposed in the experiment and demonstrated effectively to improve the signal to noise ratio.The key technique in our proposed method is a Greek-ladder sieve array,which acts as not only a wave-front modulator but also a beam splitter.With advantages of the common path,single shot,and no need for a lens,this system has enormous potential in imaging and especially in extreme ultraviolet and soft X-ray holography.     

三色圆偏振激光组合脉冲驱动氦原子产生椭圆偏振的阿秒脉冲

我们提出利用频率为ω,3ω和强度较弱的2ω组成的三色圆偏振激光组合脉冲驱动氦原子能够得到椭偏率较大的阿秒脉冲链的一种方法.通过强场近似方法,计算了氦原子在两色和三色圆偏振激光组合脉冲驱动下发射高次谐波谱及其合成阿秒脉冲链,比较了氦原子(初态为s态)在这两种情况下发射高次谐波谱的特点及其合成阿秒脉冲链椭偏率的大小,结果发现,在反旋的两色ω,3ω激光脉冲基础上加入了频率为2ω的第三色激光脉冲联合作用到氦原子上,所得到的阿秒脉冲链的椭偏率相对于双圆场情况下有所增加,通过调整ω,3ω激光的强度比,并且选择适当的第三色激光的强度,对初态为s态的原子,仍能够得到具有较大椭偏率的阿秒脉冲链.     

Enantioselective Copper‐Catalyzed Azide–Alkyne Click Cycloaddition to Desymmetrization of Maleimide‐Based Bis(alkynes)

A copper catalyst system derived from TaoPhos and CuF₂ was used successfully for catalytic asymmetric Huisgen [3+2] cycloaddition of azides and alkynes to give optically pure products containing succinimide‐ and triazole‐substituted quaternary carbon stereogenic centers. The desired products were obtained in good yields (60–80 %) and 85:15 to >99:1 enantiomeric ratio (e.r.) in this click cycloaddition reaction.     

Synthesis of Mesoporous Wall‐Structured TiO2 on Reduced Graphene Oxide Nanosheets with High Rate Performance for Lithium‐Ion Batteries

Mesoporous wall‐structured TiO₂ on reduced graphene oxide (RGO) nanosheets were successfully fabricated through a simple hydrothermal process without any surfactants and annealed at 400 °C for 2 h under argon. The obtained mesoporous structured TiO₂–RGO composites had a high surface area (99 0307 m² g^?1) and exhibited excellent electrochemical cycling (a reversible capacity of 260 mAh g^?1 at 1.2 C and 180 mAh g^?1 at 5 C after 400 cycles), demonstrating it to be a promising method for the development of high‐performance Li‐ion batteries.